Characterization of Palm Oil as Base Feedstock for Bio-lubricant Production

Authors

  • Rachel S. Ugye Kaduna Polytechnic,Kaduna, Nigeria
  • Bothwell Batidzirai 0000-0001-9998-4983
  • Edmund C. Okoroigwe University of Nigeria, Nigeria

DOI:

https://doi.org/10.31695/IJASRE.2021.33932

Keywords:

Bio-lubricant, Base oil, Biodegradable oil, Palm oil, Lubrication, Viscosity index

Abstract

Petroleum-based lubricants have dominated the range of lubricants in industrial and domestic machinery. With the global call to the reduction in fossil fuel consumption and the finite nature of petroleum deposit, interest is increasing in finding alternative lubricants that are environmentally friendly and cost-effective. One of such alternatives is lubricant from biomaterials (biomass). In this study, the characterization of palm Oil (oil) as a base oil for bio-lubricant production is carried out with a view to determining the inherent properties of the oil necessary for its use as the base oil for bio-lube production. Three samples of raw palm oil were sourced from open markets within the South-West, South-East and South-South regions in Nigeria. Each of the samples was divided into two in which one half was bleached and the other used as supplied. Prior to bleaching, the sample was degummed, neutralised and then bleached to improve their qualities. Kaolin clay was used to produce the bleaching agent used to bleach the samples. The raw and bleached samples were analysed for their respective lubricating characteristics. The physicochemical properties were tested for and compared with two commercial petroleum-based lubricants. The results show that raw palm oil has inherent lubricating properties that could enable its use as the base oil for bio-lubricants production. It was also observed that irrespective of the source of the oils, all the raw palm oil samples have similar viscosity with the same pattern of viscosity variation with temperature. Furthermore, there was a positive bleaching effect on all the properties of the oils such as improved colour, acid levels, reduced volatile content, high flash point and density.

References

Arumugam, S., Sriram, G. & Santhanam, V., 2012. FormulationofGreencrankcaseoil. A novel approach.. s.l., IEEE–Int.Conf.Adv.Eng.,25–30.

Asadauskas, S., Perez, J. & Duda, J., 1997. Lubrication properties of castor oil-potential basestoke for biodegradable lubricants. Lubrication Engineering, Volume 53, pp. 35-40.

Bhat, S. & Bekal, N. R., 2012. Bio-lubricant as an alternative to mineral oil for a CI engine–an experimental investigation with Pongamia oil as a lubricant.. Energy Sources, PartA, Volume 34, p. 1016–1025.

Campanella, A., Rustoy, E., Baldessari, A. & Baltanás, M., 2010. Lubricants from chemically modified vegetable oils. Bioresour Technology, Volume 101, p. 245–254.

D¨orm˝o, N. et al., 2004. Manufacture of an environmental-safe bio lubricant from fusel oil by enzymatic esterification in solvent-free system. Biochemical Engineering Journal, Volume 21, p. 229–234.

Darfizzi, D. & Jumat, S., 2013. Palm Oil Based bio lubricant base stocks: Synthesis, characterization, Tribological and rheological analysis. The Malaysian Journal of Analytical Sciences, 17(1), pp. 153-163.

Doll, K. & Sharma, B., 2012. Physical properties study on partially bio-based lubricant blends: thermally modified soybean oil.. International Journal Sustainable Energy, Volume 5, p. 33–37.

EPOA, 2015. European Palm Oil Alliance. [Online]

Available at: http://www.palmoilandfood.eu/en/fatty-acid-composition

[Accessed 26 September 2015].

Erhan, S. & Adhvaryu, A., 2002. Epoxidized soybean oil as a potential source of high-temperature lubricants. Industrial Crops and Products, Volume 15, p. 247–254.

Erhan, S. & Asaduaskas, S., 2000. Lubricant base stocks from vegetable oils. Industrial Crops production, Volume 11, pp. 277-82.

Global Palm Oil Conference, 2015. An overview of the palm oil sector: countries and companies, Bogota, Colombia: Global Palm Oil Conference.

Honary, L., 2010. Biodegradable/biobased lubricants and greases. Machinery Lubrication.

Honary, L. & Richter, E., 2011. Biobased Lubricants and Greases. West Sussex: John Wiley and Sons Ltd.

Ing, C. T., Rafiq, A., Azli, Y. & Syahrullail, S., 2012. Tribological behavior of refined bleached and deodorized palm oil in different loads using a four-ball tribotester. Scientia Iranica, 19(6), p. 1487–1492.

Jayadas, N. H. & Nair, K. P., 2006a. Coconut oil as a base oil for industrial lubricants — evaluation and modification of thermal, oxidative and low-temperature properties. Tribol.Int., Volume 39, p. 873–878.

Jayadas, N., Nair, K. & Ajithkumar, G., 2007. Tribological evaluation of coconut oil as an environment friendly lubricant. Tribology International, Volume 40, pp. 350-4.

Mannekote, J. K. & Kailas, S. V., 2011. Experimental investigation of coconut and palm oil as lubricants in four-stroke engine.. Tribology, Volume 6, pp. 76-82.

Mobarak, H. et al., 2014. The prospects of biolubricants as alternatives in automotive applications. Renewable and Sustainable Energy Reviews, Volume 33, pp. 34-43.

Musa, J. J., 2010. Evaluation of the Lubricating Properties of Palm Oil. Leonardo Electronic Journal of Practices and Technologies, Issue 17, pp. 79-84.

Mustapha, S., Mohammed, A., Zakari, A. & Mohammed, H., 2013. Performance evaluation of local clays from northern Nigeria for the refining of palm oil. Journal of Chemical Engineering and Materials Science, 4(5), pp. 58-66.

Nynas Corporation, 1997. Base Oil Handbook, Stockholm, Sweden: Nynas Corporation.

Okolo, J. C. & Adejumo, B. A., 2014. Effect of Bleaching on Some Quality Attributes of Crude Palm Oil. IOSR Journal of Engineering (IOSRJEN), 04(12), pp. 25-28.

Quinchia, L. et al., 2010. Viscosity modification of different vegetable oils with EVA copolymer for lubricant applications. Industrial Crops and Products, Volume 32, p. 607–612.

Rani, S., Joy, M. & Prabhakaran, K., 2015. Evaluation of physiochemical and tribological properties of rice bran oil – biodegradable and potential basestoke for industrial lubricants. Industrial Crops and Products, Volume 65, pp. 328-333.

Salih, N., J. J., Yousif, E. & Abdullah, B., 2013. Biolubricant basestocks from chemically modified plant oils: ricinoleic acid-based-tetra esters. Chemistry Central Journal, 7(1), p. 128.

Salih, N., Salimon, J. & Yousif, E., 2011. The physicochemical and tribological properties of oleic acid based triester bio-lubricants. Industrial Crops and Products, Volume 34, pp. 1089 - 1096.

Salih, N., Salimon, J., Yousif, E. & Abdullah, B., 2013. Biolubricant basestocks from chemically modified plant oils: ricinoleic acid-based-tetra esters. Chemistry Central Journal, 7(1), p. 128.

Salunkhe, J., Chavan, J., Adsule, R. & Kadem, S., 1992. World Oilseeds: Chemistry, Technology, and Utilization, New York: Van Nostrand Reinhold.

Shahabuddin, M. et al., 2013. Comparative tribological investigation of bio-lubricant formulated from a non-edible oil source (Jatropha oil). Industrial Crops and Products, Volume 47, pp. 323-330.

Tung, S. & McMillan, M., 2004. Automotive tribology overview of current advances and challenges for the future.. Tribology International, Volume 37, pp. 517-36.

UFA, 2008. Lubricant Handbook, s.l.: UFA-Chevron.

Yeong, S., OoI, T. & Salmiah, A., 2014. Bio-lubricants from palm oil, Selangor: Malaysian Palm Oil Board.

Published

2021-02-24

How to Cite

Rachel S. Ugye, Batidzirai, B. ., & Edmund C. Okoroigwe. (2021). Characterization of Palm Oil as Base Feedstock for Bio-lubricant Production. International Journal of Advances in Scientific Research and Engineering, IJASRE (ISSN: 2454 - 8006), 7(2), 56-64. https://doi.org/10.31695/IJASRE.2021.33932