Influence of PH, Immersion Time and Inhibitor Concentration on the Corrosion Inhibition Characteristic of Citrullus Lanatus Extract on A36 Carbon Steel in A CO2 Saline Solution

Authors

  • Afoegba Clement . S Petroleum Training Institute (PTI), Nigeria
  • Agbonkhese, Kingsley A National Institute of Construction Technology and Management (NICTM), Nigeria
  • Onobrenufe, Oghenero Thermosteel Nigeria Limited (Analytical/ Environmental Laboratory), Nigeria

DOI:

https://doi.org/10.31695/IJASRE.2020.33939

Keywords:

Immersion, Inhibitors, Corrosion, Citrullus Lanatus, Characteristics

Abstract

The use of Watermelon Seed Extract was employed to monitor the corrosion process of A36 Carbon Steel using varying pH (3.15-8.0), Immersion Time (24hrs-120hrs) and Inhibitor Concentration (50-200ppm). A 3.5wt% Sodium Chloride solution was prepared by dissolving 3.5g of NaCl in deionised water. Carbon (IV) oxide gas was bubbled onto the saline solution with the corresponding Ph measured and recorded using a calibrated Ph Meter (HANNA). Varying concentration (50-200ppm) of the Inhibitor was introduced into the Solution. A36 Carbon Steel Coupon was immersed into the CO2 Saline solution of varying PH. Weight Loss and Inhibition Efficiency was employed to test the investigation. Scanning Electron Microscope Analysis on the surface morphology of the Carbon Steel Coupon with and without the Inhibitor was carried out to corroborate the findings.

References

Abbasov,V.M, Hany, M. Abd El-Lateef, L. I. Aliyeva, I. T. Ismayilov and Qasimov, E. E. 2013 J. Korean Chem. Soc., , 57, no. 1, 25.

Al-Haj-Ali, A.M., Jarrah, N.A., Mu’Azu, N.D., Rihan, R.O., 2014. Thermodynamics and kinetics of inhibition of

aluminum in hydrochloric acid by date palm leaf extract. J. Appl. Sci. Environ. Manag. 18, 543–551.

Anbarai, C., Rajendran, S., Pandiarajan, M., and Krishnaveni,A ., 2013, An Encounter with Corrosion Inhibitors,

European Chemical Bulletin, vol. 2, no. 4, pp. 197-207.

Aribo, S., Olusegun, S.J., Ibhadiyi, L.J., Oyetunji, A., Folorunso, D.O., 2017. Green inhibitors for corrosion

Protection in acidizing oilfield environment. J. Assoc. Arab Univ. Basic Appl. Sci. 24, 34–38.

https://doi.org/10.1016/j.jaubas.2016.08.001

Asadi, V., Danaee, I., Eskandari, H., 2015. The Effect of Immersion Time and Immersion Temperature on the

Corrosion Behavior of Zinc Phosphate Conversion Coatings on Carbon Steel. Mater. Res. 18, 706-

https://doi.org/10.1590/1516-1439.343814

Cen, H., Chen, Z., Guo, X., 2019. N, S co-doped carbon dots as effective corrosion inhibitor for carbon steel in

CO2-saturated 3.5% NaCl solution. J. Taiwan Inst. Chem. Eng. 99, 224–238.

Chakravarthy, M.P., Mohana, K.N., 2014. Adsorption and Corrosion Inhibition Characteristics of Some

Nicotinamide Derivatives on Mild Steel in Hydrochloric Acid Solution. ISRN Corros. 2014, 1–13.

https://doi.org/10.1155/2014/687276

Chaouiki, A., Chafiq, M., Lgaz, H., Al-Hadeethi, M.R., Ali, I.H., Masroor, S., Chung, I.-M., 2020. Green Corrosion

Inhibition of Mild Steel by Hydrazone Derivatives in 1.0 M HCl. Coatings 10, 640.

Chesnokova, M.G., Shalaj, V.V., Kraus, Y.A., Cherkashina, N.V., Mironov, A.Y., 2016. Analysis of corrosion

defects on oil pipeline surface using scanning electron microscopy and soil thionic and sulfate-reducing bacteria

quantification. Procedia Eng. 152, 247–250.

Dehghani, A., Bahlakeh, G., Ramezanzadeh, B., Ramezanzadeh, M., 2019. A combined experimental and

theoretical study of green corrosion inhibition of mild steel in HCl solution by aqueous Citrullus lanatus fruit (CLF)

extract. J. Mol. Liq. 279, 603–624.

Durowaye, S.I., Alabi, A.G.F., Sekunowo, O.I., Bolasodun, B., Rufai, I.O., 2014. Effects of pH Variation on

Corrosion of Mild Steel in Bore-hole Water using 1M Sodium Hydroxide Solution. Int. J. Eng. Technol. 4, 7.

El-Lateef, H.M.A., Aliyeva, L.I., Abbasov, V.M., Ismayilov, T.I., 2012. Corrosion inhibition of low carbon steel

in CO2 -saturated solution using Anionic surfactant 17.

Espinoza Vázquez, A., López Reséndiz, L.A., Figueroa, I.A., Rodríguez Gómez, F.J., Figueroa, M., Ángeles

Beltrán, D., Castro, M., Miralrio, A., 2020. Corrosion inhibition assessment on API 5L X70 steel by preussomerin

G immersed in saline and saline acetic. J. Adhes. Sci. Technol. 1–27.

Farhadian, A., Rahimi, A., Safaei, N., Shaabani, A., Abdouss, M., Alavi, A., 2020. A theoretical and experimental

study of castor oil-based inhibitor for corrosion inhibition of mild steel in acidic medium at elevated temperatures.

Corros. Sci. 175, 108871.

Fayomi, O.S.I., Akande, I.G., Nsikak, U., 2019. An Overview of Corrosion Inhibition using Green and Drug

Inhibitors. J. Phys. Conf. Ser. 1378, 022022. https://doi.org/10.1088/1742-6596/1378/2/022022

Gerengi, H.; Uygur, I.; Solomon, M.; Yildiz, M.; Goksu, H. 2016 Evaluation of the inhibitive effect of Diospyros

kaki (Persimmon) leaves extract on St37 steel corrosion in acid medium. Sustain. Chem. Pharm., 4, 57–66.

Go, L.C., Holmes, W., Hernandez, R., 2019. Sweet corrosion inhibition on carbon steel using waste activated

sludge extract, in: 2019 IEEE Green Technologies Conference (GreenTech). IEEE, pp. 1–4.

Hassan, K.H., Khadom, A.A., Kurshed, N.H., 2016. Citrus aurantium leaves extracts as a sustainable corrosion

inhibitor of mild steel in sulfuric acid. South Afr. J. Chem. Eng. 22,1–5.

Hribšek, U., n.d. Introduction to corrosion 12.

Hu, K.; Zhuang, J.; Zheng, C.; Ma, Z.; Yan, L.; Gu, H.; Zeng, X.; Ding, J (2016). Effect of novel cytosine-l-

alanine derivative based corrosion inhibitor on steel surface in acidic solution. J. Mol. Liq., 222, 109–117

Husaini, M., Usman, B., Ibrahim, M.B., 2018. Evaluation of corrosion behaviour of aluminum in different

environment. Bayero J. Pure Appl. Sci. 11, 88–92.

Hynes, N.R.J., Selvaraj, R.M., Mohamed, T., Mukesh, A.M., Olfa, K., Nikolova, M.P., 2020. Aerva lanata flowers

extract as green corrosion inhibitor of low-carbon steel in HCl solution: an in vitro study. Chem. Pap. 1–10.

John, S., Salam, A., Baby, A.M., Joseph, A., 2019. Corrosion inhibition of mild steel using chitosan/TiO2

nanocomposite coatings. Prog. Org. Coat. 129, 254–259.

Khan, G., Basirun, W.J., Kazi, S.N., Ahmed, P., Magaji, L., Ahmed, S.M., Khan, G.M., Rehman, M.A., Badry,

A.B.B.M., 2017. Electrochemical investigation on the corrosion inhibition of mild steel by Quinazoline Schiff

base compounds in hydrochloric acid solution. J. Colloid Interface Sci. 502, 134–145.

Kina, A.Y. and Ponciano, J.A.C.(2013). Inhibition of Carbon Steel CO2 Corrosion in high salinity solutions. Int. J.

Electrochem Sci. 8, 12600-12612

Kumar, K.P.V.; Pillai, M.S.N.; Thusnavis, G.R. 2011 Seed Extract of Psidiumguajava as Ecofriendly Corrosion

Inhibitor for Carbon Steel in Hydrochloric Acid Medium.J. Mater. Sci. Technol., 27, 1143–1149.

Loto, R.T., 2018. Surface coverage and corrosion inhibition effect of Rosmarinus officinalis and zinc oxide on the

electrochemical performance of low carbon steel in dilute acid solutions. Results Phys. 8, 172–179.

https://doi.org/10.1016/j.rinp.2017.12.003

Lyon, S.; Bingham, R.; Mills, D. 2017 Corrosion Protection of Carbon Steel by Pongamiaglabra Oil- Based

Polyetheramide Coatings.Prog. Org. Coat., 102, 2–7.

Mohammed, A.A., Manalo, A.C., Ferdous, W., Zhuge, Y., Vijay, P.V., Pettigrew, J., 2020. Experimental and

numerical evaluations on the behaviour of structures repaired using prefabricated FRP composites jacket. Eng.

Struct. 210, 110358.

Muthukrishnan, P.; Prakash, P.; Jeyaprabha, B.; Shankar, K. 2019. Stigmasterol extracted from Ficushispida

leaves as a green inhibitor for the mild steel corrosion in 1 M HCl solution. Arab. J. Chem., 12, 3345–3356.

Nam, N.D., Bui, Q.V., Mathesh, M., Tan, M.Y.J., Forsyth, M., 2013. A study of 4-carboxyphenylboronic acid as a

corrosion inhibitor for steel in carbon dioxide containing environments. Corros. Sci. 76, 257–266.

Obot, I.B., Onyeachu, I.B., Umoren, S.A., 2019. Alternative corrosion inhibitor formulation for carbon steel in

CO2-saturated brine solution under high turbulent flow condition for use in oil and gas transportation pipelines.

Corros. Sci. 159, 108140.

Odewunmi, N.; Umoren, S.; Gasem, Z.; Ganiyu, S.; Muhammad, Q. 2015 Electrochemical and quantum chemical

studies on carbon steel corrosion protection in 1MH2SO4 using new eco-friendly Schi_ base metal complexes.J.

Taiwan Inst. Chem. Eng., 51, 177–185.

Oloruntoba, D.T., Adesina, O.S., Falana, O., Akinluwade, K.J., 2020. Effect of Preheat Treatment on Wear and

Corrosion Rates of Copper Electrodeposition on Medium-Carbon Steel. J. Fail. Anal. Prev. 20, 1754–1764.

Onyeachu, I.B., Obot, I.B., Adesina, A.Y., 2020. Green corrosion inhibitor for oilfield application II: The time

evolution effect on the sweet corrosion of API X60 steel in synthetic brine and the inhibition performance of 2-(2-

pyridyl) benzimidazole under turbulent hydrodynamics. Corros. Sci. 108589.

Palumbo, G., Górny, M., Banaś, J., 2019. Corrosion Inhibition of Pipeline Carbon Steel (N80) in CO2-Saturated

Chloride (0.5 M of KCl) Solution Using Gum Arabic as a Possible Environmentally Friendly Corrosion Inhibitor

for Shale Gas Industry. J. Mater. Eng. Perform. 28, 6458–6470. https://doi.org/10.1007/s11665-019-04379-3

Peng, S. and Zeng, Z. 2015 "An experimental study on the internal corrosion of a subsea multiphase pipeline"

, Petroleum, vol. 1, no. 1, pp. 75-81.

Qian, L.I., Sha-lin, Z., Zhen-bo, L.V., 2009. SYNERGISTIC INHIBITION EFFECT OF IMIDAZOLINE

QUATEMARY-AMMONIUM-SALT AND ALKYL-PHOSPHATE ESTER IN A CO2-SATURATED

ARTIFICIAL BRINE. Corros. Sci. Protetion Technol. 21, 571–573.

Ramezanzadeh, M., Bahlakeh, G., Sanaei, Z., Ramezanzadeh, B., 2019. Corrosion inhibition of mild steel in 1 M

HCl solution by ethanolic extract of eco-friendly Mangifera indica (mango) leaves: electrochemical, molecular

dynamics, Monte Carlo and ab initio study. Appl. Surf. Sci. 463, 1058–1077.

Rivera-Grau, L.M., Casales, M., Regla, I., Ortega-Toledo, D., Cuervo, D., Asencio, J., Gonzalez-Rodriguez, J., M

Martine-Gomez, L., 2012. Corrosion inhibition by a coconut oil modified imidazoline for carbon steel under the

combined effect of CO 2 and H 2 S. Int J Electrochem Sci 7, 12610–12620.

Salman, T.; Al-Azawi, K.; Mohammed, I.; Al-Baghdadi, S.; Al-Amiery, A.; Gaaz, T. 2018 Experimental and

quantum chemical simulations on the corrosion inhibition of mild steel by 3-((5-(3,5-dinitrophenyl)-1,3,4-

thiadiazol-2-yl)imino)indolin-2-one. Results Phys., 10, 291–296.

Singh, A., Ansari, K.R., Haque, J., Dohare, P., Lgaz, H., Salghi, R., Quraishi, M.A., 2018. Effect of electron

donating functional groups on corrosion inhibition of mild steel in hydrochloric acid: Experimental and quantum

chemical study. J. Taiwan Inst. Chem. Eng. 82, 233–251.

Taheri, M., Naderi, R., Saremi, M., Mahdavian, M., 2017. Development of an ecofriendly silane sol-gel coating

with zinc acetylacetonate corrosion inhibitor for active protection of mild steel in sodium chloride solution. J. Sol-

Gel Sci. Technol. 81, 154–166.

Tariq Saeed, M., Saleem, M., Niyazi, A.H., Al-Shamrani, F.A., Jazzar, N.A., Ali, M., 2020. Carrot (Daucus Carota

L.) Peels Extract as an Herbal Corrosion Inhibitor for Mild Steel in 1M HCl Solution. Mod. Appl. Sci. 14, 97.

https://doi.org/10.5539/mas.v14n2p97.

Tasić, Ž.Z., Mihajlović, M.B.P., Radovanović, M.B., Simonović, A.T., Antonijević, M.M., 2018. Cephradine as

corrosion inhibitor for copper in 0.9% NaCl solution. J. Mol. Struct. 1159, 46–54.

Uddin, I., Khan, M.A., Ullah, S., Islam, S., Israr, M., Hussain, F., 2018. Characteristics of buoyancy force on

stagnation point flow with magneto-nanoparticles and zero mass flux condition. Results Phys. 8, 160–168.

https://doi.org/10.1016/j.rinp.2017.10.038

Verma, C., Ebenso, E.E., Quraishi, M.A., 2017. Corrosion inhibitors for ferrous and non-ferrous metals and alloys

in ionic sodium chloride solutions: A review. J. Mol. Liq. 248, 927–942.

Yabuki, A.; Tanabe, S.; Fathona, I. 2018, Comparative studies of two benzaldehydethiosemicarbazone derivatives

as corrosion inhibitors for mild steel in 1.0 M HCl. Surf. Coat. Technol. 341, 71–77.

Yao, J., Ge, H., Zhang, Y., Wang, X., Xie, S., Sheng, K., Meng, X. and Zhao, Y. (2020). Influence of Ph on

corrosion inhibition of Carbon Steel in simulated cooling water containing scale and corrosion Inhibitors.

Materials and Corrosion, 71(8).Pp 110-114

Zhang, J.; Qiao, G.; Hu, S.; Yan, Y.; Ren, Z.; Yu, L. 2011. Theoretical evaluation of corrosion inhibition

performance of imidazoline compounds with di_erent hydrophilic groups. Corros. Sci., 53, 147–152

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Afoegba Clement . S, Agbonkhese, Kingsley A, & Onobrenufe, Oghenero. (2020). Influence of PH, Immersion Time and Inhibitor Concentration on the Corrosion Inhibition Characteristic of Citrullus Lanatus Extract on A36 Carbon Steel in A CO2 Saline Solution. International Journal of Advances in Scientific Research and Engineering (IJASRE), ISSN:2454-8006, DOI: 10.31695/IJASRE, 6(12), 56–76. https://doi.org/10.31695/IJASRE.2020.33939

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Vol. 6 No. 12: December-2020

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