Preparation, Characterization and Antimicrobial Studies of Cu (II) and Mn (II) Complexes with Schiff Base Derived from Benzaldehyde and 2,4-Dinitrophenylhydrazine

Authors

  • S.D Sardo Kano University of Science and Technology, Wudil, Kano-Nigeria
  • S. S. Bashir Kano University of Science and Technology, Wudil, Kano-Nigeria
  • A. Abdulmalik Rabi`u Musa Kwankwaso College of Advance and Remedial Studies T/Wada, Kano-Nigeria
  • A. Baffa Rabi`u Musa Kwankwaso College of Advance and Remedial Studies T/Wada, Kano-Nigeria
  • A.A Muhammad Rabi`u Musa Kwankwaso College of Advance and Remedial Studies T/Wada, Kano-Nigeria
  • A.N Panda Rabi`u Musa Kwankwaso College of Advance and Remedial Studies T/Wada, Kano-Nigeria
  • Yahaya sa`idu Rabi`u Musa Kwankwaso College of Advance and Remedial Studies T/Wada, Kano-Nigeria

DOI:

https://doi.org/10.31695/IJASRE.2021.34017

Keywords:

Schiff base, Benzaldehyde, 2,4-Dinitrophenylhydrazine , Antimicrobial activities

Abstract

Two series of Cu(II) and Mn(II) complexes were prepared by refluxing ethanolic solution of their salts with Schiff base obtained from benzaldehyde and 2,4-dinitrophenylhydrazine into a 1:2 ratio. The prepared compounds were characterized by solubility, molar conductance, and infrared analysis. The complexes show low molar conductance values suggesting non-electrolytic nature. The Schiff ligand and its metal (II) complexes were found to be active against four isolates of bacteria (Salmonella bongori, Streptococcus pyogenes, Staphylococcus aureus and Shingella dysenteriae).

References

Adhikari, D. and Prakash, A. (2011). Application of Schiff bases and their metal complexes. A Review. Int. J. ChemTech Res.3, 1891-1896.

Murugavel, R , Choudhury,A and Walawalker, M.G. (2008). Metal complexes of Organo-phosphate esters and open-framework metal phosphate: synthesis, structure, Transformations, and applications. Chemical Reviews, 108: 3549-3655.

Xishi, T., Xian, H. Y., Qiang, C. and Minyu, T., (2003), “Synthesis of Some Transition Metal Complexes of a Novel Schiff Base Ligand Derived from 2, 2’ – Bis(p-Methoxy Phenylamine) and Salicylic Aldehyde ”, Molecules, 8: 439-443

Dobrokhotova, Z, Emelina, Aand Sidorov, A. (2011). Synthesis, characterization of Li(I)M(II) (M=Co, Ni) heterometallic complexes as molecular precursors for LiMO2. Polyhedron, 30: 132-141

Ndahi, N.P and Nasiru Y.P (2012). complexes of Co(II), Ni(II), and Zn(II) with Schiff bases derived 4-anisaldehyde with 2,4 dinitrophenylhydrazine. International Journal of Pharmaceutical Sciences and Research,3:5116-5120.

Salawu, O.W and Abdilsalam, A.O (2011). Synthesis, characterization and biological activities of Cd (II) complexes with hydrazine ligands; Scholars Research Library Der PharmaChemica, 3(4):298-304.

Christoph, J., Hassan, H.M. and Omid, P. (2007). Synthesis and Spectral Characterization of Hydrazone Schiff Bases Derived from 2,4-Dinitrophenylhydrazine.Crystal Structure of Salicylaldehyde-2,4-Dinitrophenylhydrazone.Chemical Sciences Zeitschrift fur Natur- forschung B 62:717 – 720

Ramon N, Mutijuraj V, Rovichandran S, Kulandaisamy A (2003). Synthesis, Characterization and Electrochemical Behavior of Cu(II), Fe(II), Co(II), Ni(II) and Zn(II) Complexes derived from acetylacetone and p-anisidine and their Antimicrobial Activity, Proc. Ind. Acad. Sci. 115(5): 161 – 167

Yeamin R. Belayet H. and Saidul Islam M. (2003). Antimicrobial Studies of Mixed Ligand Transition Metal Complexes of Phthalic acid and heterocyclic amine Bases. Pakistan J. Biological sciences. 6(17): 1494-1496

Bhatt V.D and Ray A, (2001). Synthesis, characterization and electrical conductivity of

polyester containing azomethine linkages. International Journal of Polymeric Materials,

: 355-366.

11. Zahid H.C and Maimoon F.J (2001) Synthesis, Characterization and Biological Evaluation

of Co (II), Ni(II) and Zn(II) Complexes with cephradine, metal Based drugs 7:265-269

Nakamato k ( 1971).Infrared spectra of inorganic and coordination compounds, John Wiley and Sons, New York.

Tweedy, B.G (1964). Plant Extracts With Metal Ions As Potential Agents,Psychology , Scientific Research J.55:910-918

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How to Cite

S.D Sardo, S. S. Bashir, A. Abdulmalik, A. Baffa, A.A Muhammad, A.N Panda, & Yahaya sa`idu. (2021). Preparation, Characterization and Antimicrobial Studies of Cu (II) and Mn (II) Complexes with Schiff Base Derived from Benzaldehyde and 2,4-Dinitrophenylhydrazine. International Journal of Advances in Scientific Research and Engineering (IJASRE), ISSN:2454-8006, DOI: 10.31695/IJASRE, 7(6), 88–92. https://doi.org/10.31695/IJASRE.2021.34017

Issue

Vol. 7 No. 6 (2021): June-2021

Section

Articles

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Copyright (c) 2021 S.D Sardo , S. S. Bashir , A. Abdulmalik , A. Baffa, A.A Muhammad , A.N Panda, Yahaya sa`idu

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